The discovery of the natural radioactive decay of uranium in 1896 by Henry Becquerel, the French physicist, opened new vistas in science. In 1905, the British physicist Lord Rutherford--after defining the structure of the atom-- made the first clear suggestion for using radioactivity as a tool for measuring geologic time directly; shortly thereafter, in 1907, Professor B. B. Boltwood, radiochemist of Yale Uniyersity, published a list of geologic ages based on radioactivity. Although Boltwood's ages have since been revised, they did show correctly that the duration of geologic time would be measured in terms of hundreds-to-thousands of millions of years.
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| A technician of the U.S. Geological Survey uses a mass spectrometer to determine the proportions of neodymium isotopes contained in a sample of igneous rock. |
The next 40 years was a period of expanding research on the nature and behavior of atoms, leading to the development of nuclear fission and fusion as energy sources. A byproduct of this atomic research has been the development and continuing refinement of the various methods and techniques used to measure the age of Earth materials. Precise dating has been accomplished since 1950.
A chemical element consists of atoms with a specific number of protons in their nuclei but different atomic weights owing to variations in the number of neutrons. Atoms of the same element with differing atomic weights are called isotopes. Radioactive decay is a spontaneous process in which an isotope (the parent) loses particles from its nucleus to form an isotope of a new element (the daughter). The rate of decay is conveniently expressed in terms of an isotope's half-life, or the time it takes for one-half of a particular radioactive isotope in a sample to decay. Most radioactive isotopes have rapid rates of decay (that is, short half-lives) and lose their radioactivity within a few days or years. Some isotopes, however, decay slowly, and several of these are used as geologic clocks. The parent isotopes and corresponding daughter products most commonly used to determine the ages of ancient rocks are listed below:
| Parent Isotope | Stable Daughter Product | Currently Accepted Half-Life Values |
| Uranium-238 | Lead-206 | 4.5 billion years |
| Uranium-235 | Lead-207 | 704 million years |
| Thorium-232 | Lead-208 | 14.0 billion years |
| Rubidium-87 | Strontium-87 | 48.8 billion years |
| Potassium-40 | Argon-40 | 1.25 billion years |
| Samarium-147 | Neodymium-143 | 106 billion years |
| Carbon samples are converted to acetylene gas by combustion in a vacuum line. The acetylene gas is then analyzed in a mass spectrometer to determine its carbon isotopic composition. |
Most sedimentary rocks such as sandstone, limestone, and shale are related to the radiometric time scale by bracketing them within time zones that are determined by dating appropriately selected igneous rocks, as shown by a hypothetical example.
Literally thousands of dated materials are now available for use to bracket the various episodes in the history of the Earth within specific time zones. Many points on the time scale are being revised, however, as the behavior of isotopes in the Earth's crust is more clearly understood. Thus the graphic illustration of the geologic time scale, showing both relative time and radiometric time, represents only the present state of knowledge. Certainly, revisions and modifications will be forthcoming as research continues to improve our knowledge of Earth history.
This page is URL: <https://pubs.usgs.gov/gip/geotime/radiometric.html>
Last updated June 13, 2001